Prepare the Brownie Base: Preheat your oven to 350°F (175°C). Grease a 9x13 inch baking pan and line it with parchment paper, allowing some overhang for easy lifting later.
Melt the Chocolate and Butter: In a medium saucepan over low heat, combine the unsalted butter and the chopped semi-sweet chocolate. Stir continuously until the mixture is melted and smooth. Once melted, remove the saucepan from heat and let it cool for about 10 minutes.
Mix in Sugars and Eggs: In a large mixing bowl, combine the granulated sugar and brown sugar. Pour in the cooled chocolate mixture and whisk until well combined. Add the eggs, one at a time, ensuring each egg is fully incorporated before adding the next. Stir in the pure vanilla extract.
Combine Dry Ingredients: In a separate bowl, whisk together the all-purpose flour, cocoa powder, baking powder, and salt. Gradually fold this dry mixture into the wet batter. Mix gently until just combined—be careful not to overmix.
Bake the Brownies: Pour the prepared brownie batter into the lined baking pan, spreading it evenly across the surface. Bake in the preheated oven for 25-30 minutes, or until a toothpick inserted into the center comes out with a few moist crumbs. Allow the brownies to cool completely in the pan on a wire rack.
Prepare the Chocolate Mousse: In a medium saucepan, heat the heavy cream over medium heat until it barely simmers (small bubbles will form around the edges). Remove from heat, add the finely chopped dark chocolate, and stir until completely melted and smooth. Let this mixture cool for about 10 minutes.
Whip the Mousse: Transfer the cooled chocolate mixture to a mixing bowl and whip with an electric mixer until fluffy and light. Add the powdered sugar and the pure vanilla extract, continuing to whip until soft peaks form—be cautious not to overwhip the mousse.
Assemble: Once the brownies are fully cooled, pour the whipped chocolate mousse over the top, spreading it evenly. Cover with plastic wrap and chill in the refrigerator for at least 2 hours to allow the mousse to set.
Serve: After the mousse has set, use the parchment overhang to lift the brownies out of the pan. Cut into squares or rectangles for serving. They can be enjoyed chilled or at room temperature for a delightful treat.
Notes
For an extra touch, sprinkle grated chocolate or cocoa powder on top of the mousse just before serving. Add fresh berries or mint leaves for a pop of color and flavor!